CAUTION: Safety is very important when etching. Be sure to wear the appropriate protective clothing and observe all WARNINGS on chemical manufacturers .  

Etchant Composition Conc. Conditions Comments
Kellers Etch Distilled water
Nitric acid
Hydrochloric acid
Hydrofluoric acid
190 ml
5 ml
3 ml
2 ml
10-30 second immersion. Use only fresh etchant  
Kroll's Reagent Distilled water
Nitric acid
Hydrofluoric acid
92 ml
6 ml
2 ml
15 seconds  
Nital Ethanol
Nitric acid
100 ml
1-10 ml
Seconds to minutes  
Kallings Reagent Distilled water
Copper chloride (CuCl2)
Hydrochloric acid
Ethanol (85%) or Methanol (95%)
40 ml
2 grams
40 ml
40-80 ml
Immerse or swab for few seconds to a few minutes  
Lepito's Reagent Acetic acid
Nitric acid
50 ml
50 ml
Swab  
Marble's Reagent Distilled Water
Hydrochloric acid
Copper sulfate
50 ml
50 ml
10 grams
Immersion or swab
etching for a few seconds
 
Murakami Reagent Distilled Water
K3Fe(CN)8
NaOH or KOH
100 ml
10 grams
10 grams
Immerse or swab for seconds to minutes Use fresh
Picral Ethanol
Picric acid
100 ml
2-4 grams
Seconds to minutes Do not let etchant crystallize or dry -explosive
Vilella's Reagent Glycerol
Nitric acid
Hydrochloric acid
45 ml
15 ml
30 ml
Seconds to minutes  

 


Guide to Acid Concentrations

 

Acid/ Base

Specific gravity

Acid concentration

Nitric (HNO3)

1.4

68-70%

Hydrofluoric (HF)

 

40%

Hydrochloric (HCl)

 

37-38%

Ammonium Hydroxide
(NH4OH)

 

35%

 

Electrolytic etching is another fairly common etching technique. It is similar to chemical etching in that acids and bases are used for modifying the pH, however the electrochemcial potential is controlled electrically by varying the voltage and current externally as opposed to chemically. Electrolytic etching is often used for harder to etch specimens that do not respond well to basic chemical etching techniques. Electrolytic techniques require that the specimen be conductive and is therefore limited primarily to metals.

The most common electrolytic etching equipment uses a two electrode design (anode and cathode) using acids or bases for the electrolyte. Procedures for this type of electrolytic etching are fairly common .

Common Electrochemical Etchants

Application

Etchant

Conditions

Comments

Wrought stainless steel Concentrated NH4OH Stainless steel cathode
6 volts DC
Room temperature
30-60 seconds
General structure
Austenitic stainless steels 100 ml Distilled water

10 gram CrO3

3-6 volts DC

5-60 seconds

Attacks carbides and sigma phase
Copper and copper alloys (Cu) 5-14% H3PO4
Remainder water
1-4 volts DC
10 seconds
Copper and brass
Titanium (pure) 25 ml Distilled water
390 ml Methanol (95%)
Ethylene glycol
35 ml perchloric acid (70%)
Stainless steel cathode
30-50 volts DC
5-10
°C (40-50 °F)
10-40 seconds
 
Titanium carbide (TiC) 10 ml Distilled water
2 grams potassium hydroxide
Pt cathode
2 volts DC
30-60 mA/cm2
2-30 seconds
 
Wrought Fe-Ni-Cr Heat resisting alloys (Fe) 100 ml Distilled water
5 gram CrO3
Stainless steel cathode
5-10 volts DC
15-20 seconds
Room temperature
General structure
Steels 10 grams Chromic acid
100 ml Distilled water
Pt or stainless steel cathode
3-6 volts DC
5-60 seconds
Carbide and cementite etching
Nimonic alloys (Ni) 45 parts Hydrochloric acid
15 parts Nitric acid
40 parts glycerol
Stainless steel cathode
2-4 volts DC, 0.5 A/dm2
5-15 seconds
Nimonic PK31
Stainless Steels 100 ml Distilled water
10 grams oxalic acid
Stainless steel cathode
6 volts DC
Room temperature
General structure